反応式
[Cl-:1].[Mn+2:2].[Cl-].[CH2:4]([N:6]1[CH2:19][CH2:18][CH2:17][NH:16][CH2:15][CH2:14][N:13]([CH2:20][CH3:21])[CH2:12][CH2:11][CH2:10][NH:9][CH2:8][CH2:7]1)[CH3:5]>CC(N(C)C)=O>[Cl-:1].[Cl-:1].[Mn+2:2].[CH2:4]([N:6]1[CH2:19][CH2:18][CH2:17][NH:16][CH2:15][CH2:14][N:13]([CH2:20][CH3:21])[CH2:12][CH2:11][CH2:10][NH:9][CH2:8][CH2:7]1)[CH3:5]参加物
4
反応条件
- 温度
- 100 °C
実験手順
12.6 g (0.1 mol) of manganese(II) chloride were dissolved in 100 ml of DMAC. The solution was admixed with 25.6 g (0.1 mol) of 1,8-diethyl-1,4,8,11-tetraazacyclotetradecane. The reaction mixture was heated at 100° C. for 5 hours. The resulting suspension was then cooled to room temperature, and the resulting solid was filtered off, washed with 50 ml of DMAC and then dried in vacuo at a temperature of 80° C. This gave 37.1 g of the pale grey complex, which corresponds to a yield of 97.0%.
後処理
- temperatureThe resulting suspension was then cooled to room temperature
- filtrationthe resulting solid was filtered off
- washwashed with 50 ml of DMAC
- customdried in vacuo at a temperature of 80° C
出典と根拠
- ORDレコード
- ord-0c560bd7617d4406979dc099f6945af5
- 出典データセット
- uspto-grants-2015_08
- 特許番号
- US09102903B2
関連ノート
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