1-(2,4-Dichlorophenyl)-3-methylnaphthalen-2-ol → 1-(2,4-Dichlorophenyl)-3-methylnaphthalen-2-yl trifluoromethanesulfonate
反応式
[F:1][C:2]([F:20])([F:19])[S:3]([O:6][C:7]1[C:16]([CH3:17])=[CH:15][C:14]2[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=2)[C:8]=1Cl)(=[O:5])=[O:4].[Cl:21][C:22]1[CH:27]=[C:26]([Cl:28])[CH:25]=[CH:24][C:23]=1C1C2C(=CC=CC=2)C=C(C)C=1O>>[F:1][C:2]([F:20])([F:19])[S:3]([O:6][C:7]1[C:16]([CH3:17])=[CH:15][C:14]2[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=2)[C:8]=1[C:25]1[CH:24]=[CH:23][C:22]([Cl:21])=[CH:27][C:26]=1[Cl:28])(=[O:5])=[O:4]参加物
3
実験手順
1-(2,4-dichlorophenyl)-3-methylnaphthalen-2-yl trifluoromethanesulfonate was prepared in a similar manner as compound 4C in Example 2, except starting from 1-(2,4-dichlorophenyl)-3-methylnaphthalen-2-ol instead of 4B. 1H-NMR: 400 MHz, (CDCl3) δ: 7.85-7.90 (m, 2H), 7.62 (d, 1H), 7.55 (app dt, 1H), 7.41-7.48 (m, 2H), 7.32-7.49 (m, 2H), 2.64 (s, 3H).
出典と根拠
- ORDレコード
- ord-81e47063a1d647bfa293406bc2e462d5
- 出典データセット
- uspto-grants-2015_08