4-Benzyl-5-methyl-[1,4]oxazepane → 4-Benzyl-5-phenyl-1,4-oxazepane

HRID 515448ノート

反応式

HRID 515448 の反応式
C(N1C(C)CCOCC1)C1C=CC=CC=1.[CH2:16]([N:23]1[CH:29]([C:30]2[CH:35]=[CH:34][CH:33]=[CH:32][CH:31]=2)[CH2:28][CH2:27][O:26][CH2:25][C:24]1=O)[C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1>>[CH2:16]([N:23]1[CH:29]([C:30]2[CH:35]=[CH:34][CH:33]=[CH:32][CH:31]=2)[CH2:28][CH2:27][O:26][CH2:25][CH2:24]1)[C:17]1[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=1

参加物

3

反応物 2

HCID 667187904-Benzyl-5-methyl-[1,4]oxazepaneHCID 672829204-Benzyl-5-phenyl-[1,4]oxazepan-3-one

生成物 1

HCID 667185434-Benzyl-5-phenyl-1,4-oxazepane

実験手順

4-Benzyl-5-phenyl-[1,4]oxazepane was prepared by the same procedure as that of 4-benzyl-5-methyl-[1,4]oxazepane except for utilizing 4-benzyl-5-phenyl-[1,4]oxazepan-3-one instead of 4-benzyl-5-methyl-[1,4]oxazepan-3-one. 4-Benzyl-5-phenyl-[1,4]oxazepane was obtained as colorless oil (0.28 g, 1.0 mmol, 39%).

出典と根拠

ORDレコード
ord-402bd8e6445e45ddbe5ba70a43319047
出典データセット
uspto-grants-2015_08
特許番号
US09108957B2

反応ノート

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