Methanol → HCID 178448544、化合物

HRID 516650

反応式

HRID 516650 の反応式
[CH3:1][CH2:2][CH2:3][CH2:4][N:5]1[CH:9]=[N+:8]([CH3:10])[CH:7]=[CH:6]1.[Cl-].CO.[F-:14].[K+]>O>[F-:14].[CH2:4]([N+:5]1[CH:6]=[CH:7][N:8]([CH3:10])[CH:9]=1)[CH2:3][CH2:2][CH3:1]

参加物

5

反応物 3

HCID 887MethanolHCID 522689Potassium FluorideHCID 27341611-Butyl-3-methylimidazolium chloride2 回

生成物 1

HCID 178448544HCID 178448544、化合物収率 94%

試薬・触媒・溶媒 1

HCID 962Water溶媒

反応条件

温度
22 °C

実験手順

10.3 grams of [BMIMCl] prepared as described above were added to a mixture of 28 mL methanol and 0.06 mL water. After complete dissolution of the [BMIMCl], 5.0 grams of dry potassium fluoride (KF) were added, and the reaction mixture was stirred at 22° C. for 20 minutes. The mixture was filtered. 4.4 grams of KF was added to the filtrate, and the mixing continued for additional 20 minutes. After filtration, the methanol was evaporated under vacuum at room temperature, and the mixture was then filtered and centrifuged. The resulting yellowish liquid was determined by elementary analysis to be the titled compound [BMIMF] in 94% yield.

後処理

  1. additionwere added
  2. filtrationThe mixture was filtered
  3. addition4.4 grams of KF was added to the filtrate
  4. waitthe mixing continued for additional 20 minutes
  5. filtrationAfter filtration
  6. customthe methanol was evaporated under vacuum at room temperature
  7. filtrationthe mixture was then filtered

出典と根拠

ORDレコード
ord-1ab9d796dbeb4188a89ff06eca4121c7
出典データセット
uspto-grants-2015_08
特許番号
US09114360B2

関連ノート

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