Potassium Carbonate → Ethyl 4-(benzyloxy)-3-hydroxybenzoate

HRID 521518ノート

反応式

HRID 521518 の反応式
[CH2:1]([O:3][C:4](=[O:23])[C:5]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:7]([O:19]C(=O)C)[CH:6]=1)[CH3:2].C(=O)([O-])[O-].[K+].[K+]>CO>[CH2:1]([O:3][C:4](=[O:23])[C:5]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:7]([OH:19])[CH:6]=1)[CH3:2]

参加物

4

反応物 2

HCID 11430Potassium CarbonateHCID 67170201HCID 67170201、化合物

生成物 1

HCID 11311797Ethyl 4-(benzyloxy)-3-hydroxybenzoate

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

The compound of step 1 (10 g, 31.8 mmol) was dissolved in methanol, potassium carbonate (88 mg, 0.636 mmol) was added and the mixture was stirred for 2 h under reflux. After evaporation to dryness, the residue was used without further purification in the subsequent step.

後処理

  1. temperatureunder reflux
  2. customAfter evaporation to dryness
  3. customthe residue was used without further purification in the subsequent step

出典と根拠

ORDレコード
ord-dfacff06dd0949c28dda9c235b25f569
出典データセット
uspto-grants-2016_05
特許番号
US09328071B2

反応ノート

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