化工社化工社 化学情報印刷レポート · 研究参考用
Ethylene → 1-Decene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ethylene | HCID 6325 | — |
| 反応物 | 1-Octene | HCID 8125 | — |
| 反応物 | Palmitoleic Acid | HCID 445638 | — |
| 反応物 | Oleic Acid | HCID 445639 | — |
| 反応物 | Methyl 9-decenoate | HCID 1778877 | — |
| 生成物 | 1-Decene | HCID 13381 | — |
| 生成物 | Ethyl 9-decenoate | HCID 522255 | — |
反応手順
Ethenolysis comprises a cross-metathesis reaction involving ethene. According to some preferred embodiments of the invention, a mixture of ethyl esters of Palmitoleic acid (C16:1) and Oleic acid (C18:1) are subjected to conditions of ethenolysis to yield a mixture of α-olefins (1-Octene and 1-Decene) and Methyl 9-Decenoate. See FIG. 8. The 1-Octene is a product unique to ethenolysis of Palmitoleic acid (C16:1). In the inventive method, Ethyl 9-Decenoate and 1-Decene will also form from the mixture of Palmitoleic and Oleic acid ethyl esters. Prior art methods using Oleic acid esters (Methyl Oleate) as the starting material only produce Methyl 9-Decenoate and 1-Decene.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US09346729B2 |
| 出典データセット | uspto-grants-2016_05 |
| ORD ID | ord-da14fc64f9344f40a488584c585d418d |
| 出典メモ | uspto-grants-2016_05 |