戻る
化工社化工社 化学情報印刷レポート · 研究参考用
HRID 526659作成日:2026年10月26日

Ethylene → 1-Decene

https://huagongshe.com/reaction/526659

反応式

関与物質

役割名称HCID仕込み量
反応物EthyleneHCID 6325—
反応物1-OcteneHCID 8125—
反応物Palmitoleic AcidHCID 445638—
反応物Oleic AcidHCID 445639—
反応物Methyl 9-decenoateHCID 1778877—
生成物1-DeceneHCID 13381—
生成物Ethyl 9-decenoateHCID 522255—

反応手順

Ethenolysis comprises a cross-metathesis reaction involving ethene. According to some preferred embodiments of the invention, a mixture of ethyl esters of Palmitoleic acid (C16:1) and Oleic acid (C18:1) are subjected to conditions of ethenolysis to yield a mixture of α-olefins (1-Octene and 1-Decene) and Methyl 9-Decenoate. See FIG. 8. The 1-Octene is a product unique to ethenolysis of Palmitoleic acid (C16:1). In the inventive method, Ethyl 9-Decenoate and 1-Decene will also form from the mixture of Palmitoleic and Oleic acid ethyl esters. Prior art methods using Oleic acid esters (Methyl Oleate) as the starting material only produce Methyl 9-Decenoate and 1-Decene.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US09346729B2
出典データセットuspto-grants-2016_05
ORD IDord-da14fc64f9344f40a488584c585d418d
出典メモuspto-grants-2016_05