関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Allyl chloride | HCID 7850 | — |
| 反応物 | Triethoxysilane | HCID 13830 | — |
| 触媒 | Chloro(1,5-cyclooctadiene)iridium(I) dimer | HCID 6436381 | — |
| 溶媒 | P-Xylene | HCID 7809 | — |
| 生成物 | (3-Chloropropyl)triethoxysilane | HCID 78771 | 83% |
反応手順
In a minilab pressure reactor of the TINYCLAVE type (BUECHI) with a capacity of 25 ml, 4 g of p-xylene, 4.2 g (0. 055 mol) of allyl chloride and 8.2 g (0.05 mol) of triethoxysilane were mixed intensively with 0.16 mg (10-3 mol %) of chloro-(1,5-cyclooctadiene)iridium(I) dimer at room temperature for one hour. The reaction mixture was then heated at 80° C. for 2 hours in a thermostat. Analysis by gas chromatography gave a product yield of 83% of 3-chloropropyltriethoxysilane.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05616762 |
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| 出典データセット | uspto-grants-1997_04 |
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| ORD ID | ord-f4cb1ec4b0a1458a99cc43273097e972 |
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| 出典メモ | uspto-grants-1997_04 |
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