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Allyl chloride → (3-Chloropropyl)triethoxysilane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Allyl chloride | HCID 7850 | — |
| 反応物 | Triethoxysilane | HCID 13830 | — |
| 触媒 | Chloro(1,5-cyclooctadiene)iridium(I) dimer | HCID 6436381 | — |
| 溶媒 | P-Xylene | HCID 7809 | — |
| 生成物 | (3-Chloropropyl)triethoxysilane | HCID 78771 | 61% |
反応手順
In analogy to Example 3, a homogeneous reaction solution of 4 g of p-xylene, 3.8 g (0.05 mol) of allyl chloride (instead of 4.2 g corresponding to 0.055 mol), 8.2 g (0.05 mol) of triethoxysilane and 0.16 mg (10-3 mol %) of chloro-(1,5-cyclooctadiene)iridium(I) dimer were reacted without a relatively long mixing or storage time. Analysis by gas chromatography gave a product yield of only 61% of 3-chloropropyltriethoxysilane.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05616762 |
| 出典データセット | uspto-grants-1997_04 |
| ORD ID | ord-1046655f81d5414dad9edc05ddc70660 |
| 出典メモ | uspto-grants-1997_04 |