化工社化工社 化学情報印刷レポート · 研究参考用
3,3,3-Trifluoropropene → 3,3,3-Trifluoropropylcyclopentyldiethoxysilane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 3,3,3-Trifluoropropene | HCID 12672 | — |
| 反応物 | Cyclopentyldiethoxysilane | HCID 123987211 | — |
| 触媒 | Iridium trichloride hydrate | HCID 16211477 | — |
| 溶媒 | P-Xylene | HCID 7809 | — |
| 生成物 | 3,3,3-Trifluoropropylcyclopentyldiethoxysilane | HCID 22377678 | 77% |
反応手順
In analogy to Example 3, a mixture of 3 g of p-xylene, 5.3 g (0.055 mol) of 3,3,3-trifluoro-1-propene and 9.4 g (0.5 mol) of cyclopentyldiethoxysilane was reacted in the presence of 0.1 mg of iridium(III) chloride hydrate, after a mixing time of 70 minutes, at 83° C. over 180 minutes. Analysis by gas chromatography gave a product yield of 77% of 3,3,3-trifluoropropylcyclopentyldiethoxysilane.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05616762 |
| 出典データセット | uspto-grants-1997_04 |
| ORD ID | ord-844fb9cc8acf4c52b30fdadb2a3243f0 |
| 出典メモ | uspto-grants-1997_04 |