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HRID 529432作成日:2026年10月26日

Acrylic Acid → Phenoxyethyl acrylate methyl methacrylate acrylic acid

https://huagongshe.com/reaction/529432

反応式

関与物質

役割名称HCID仕込み量
反応物Acrylic AcidHCID 6581—
反応物Methyl MethacrylateHCID 6658—
反応物Phenoxyethyl acrylateHCID 39485—
反応物1,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis(2-methylpropanoate)HCID 75763—
溶媒IsopropanolHCID 3776—
溶媒Methyl Ethyl KetoneHCID 6569—
生成物Phenoxyethyl acrylate methyl methacrylate acrylic acidHCID 86634647—

反応条件

温度75 °C

反応手順

360.0 g of methyl ethyl ketone was added to a 2 liter three-necked flask provided with a stirrer, a thermometer, a reflux condenser, and a nitrogen gas introducing tube, followed by heating up to 75° C. Thereafter, while maintaining the temperature inside the flask at 75° C., a mixed solution of 180.0 g of phenoxyethyl acrylate, 162.0 g of methyl methacrylate, 18.0 g of acrylic acid, 72 g of methyl ethyl ketone, and 1.44 g of “V-601” (manufactured by Wako Pure Chemical Industries, Ltd.) was added dropwise thereto at a constant speed such that the dropwise addition was completed in two hours. After the completion of the dropwise addition, a solution containing 0.72 g of “V-601” and 36.0 g of methyl ethyl ketone was added thereto followed by stirring at 75° C. for 2 hours. Furthermore, a solution containing 0.72 g of “V-601” and 36.0 g of isopropanol was added thereto followed by stirring at 75° C. for 2 hours, and heated to 85° C. followed by stirring for another 2 hours, thereby obtaining a resin solution of a phenoxyethyl acrylate/methyl methacrylate/acrylic acid (=50/45/5 [mass ratio]) copolymer.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US09346968B2
出典データセットuspto-grants-2016_05
ORD IDord-674017389f9e418bb7ff83747e6836ea
出典メモuspto-grants-2016_05