関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Chlorodimethylsilane | HCID 66108 | — |
| 反応物 | 4-Pentenoic acid, phenylmethyl ester | HCID 10052035 | — |
| 生成物 | Benzyl 5-(chlorodimethylsilyl)pentanoate | HCID 90417974 | — |
反応手順
To a mixture of chlorodimethylsilane (0.730 g; 6.57 mmol) and benzyl pent-4-enoate (1.25 g; 6.57 mmol) under argon was added one drop of Karstedt's catalyst solution (in xylenes; ˜2% Pt). The reaction vessel was sealed and the mixture was heated to 60° C. for 13.5 hours. The crude liquid was used without purification.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US09352049B2 |
|---|
| 出典データセット | uspto-grants-2016_05 |
|---|
| ORD ID | ord-8f257ecde9994d4b96cd6c2c43e51915 |
|---|
| 出典メモ | uspto-grants-2016_05 |
|---|
