4-Pentenoic acid, phenylmethyl ester → HCID 90418027、化合物

反応式

[Cl:1][SiH:2]1[CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1.[C:8]([O:14][CH2:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)(=[O:13])[CH2:9][CH2:10][CH:11]=[CH2:12]>>[Cl:1][Si:2]1([CH2:12][CH2:11][CH2:10][CH2:9][C:8]([O:14][CH2:15][C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)=[O:13])[CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1

参加物

反応物 2

HCID 100520354-Pentenoic acid, phenylmethyl ester

HCID 713532331-Chlorosilinane

生成物 1

HCID 90418027HCID 90418027、化合物

反応条件

温度: 60 °C

実験手順

To a mixture of crude 1-chlorosilinane (0.35 g) and benzyl pent-4-enoate (0.50 g; 2.63 mmol) under argon was added two drops of Karstedt's catalyst solution (in xylenes; ˜2% Pt). The reaction vessel was sealed and the mixture was heated to 60° C. for 16 hours. The crude liquid was used without purification.

後処理

customThe reaction vessel was sealed
customThe crude liquid was used without purification

出典と根拠

ORDレコード: ord-5d833aab1b014d648e7249199a29c9a5
出典データセット: uspto-grants-2016_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US09352049B2

反応ノート

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