関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Cyclopentadiene | HCID 7612 | — |
| 反応物 | Maleic Anhydride | HCID 7923 | — |
| 反応物 | 5-Norbornene-2,3-dicarboxylic acid | HCID 97965 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | endo-Dicyclopentadiene | HCID 15618652 | 49% |
反応手順
Maleic anhydride (88.3 g, 0.90 mole) and water (150.0 g) was stirred at 20-30° C. under nitrogen, cyclopentadiene (30.0 g, 0.45 mole) was added dropwise over 1 hour and stirred at 25° C. for 6 hours, it was heated to 101° C. and held for 20 hours until 92% of nadic acid was converted to NBLCO2H as detected by GC. The wet crystal was filtered out and recrystallized from water to obtain 40.3 g of NBLCO2H with a yield of 49%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US09353213B2 |
|---|
| 出典データセット | uspto-grants-2016_05 |
|---|
| ORD ID | ord-ea0b2cfc69054a2e980fd4f688c47c69 |
|---|
| 出典メモ | uspto-grants-2016_05 |
|---|
