alpha-Thujene → 2-Methyl-5-(1-methylethyl)bicyclo(3.1.0)hexan-2-ol
反応式
[O-:1]O.[CH3:3][C:4]1[CH:8]2[CH2:9][C:7]2([CH:10]([CH3:12])[CH3:11])[CH2:6][CH:5]=1>[Ni]>[CH3:11][CH:10]([C:7]12[CH2:9][CH:8]1[C:4]([OH:1])([CH3:3])[CH2:5][CH2:6]2)[CH3:12]参加物
4
実験手順
The hydroperoxide resulting from α-thujene can be reduced to 4-hydroxy-β-thujene and can then be hydrogenated, e.g. in the presence of Raney nickel, to give sabinene hydrate.
出典と根拠
- ORDレコード
- ord-c8171cd5fd0b4c1a9e57d3f8d8be06ad
- 出典データセット
- uspto-grants-1997_04
- 特許番号
- US05620569
反応ノート
読み込み中…