Perhydroxyl radical → Oxiranemethanol, 3-methyl-3-(4-methyl-3-pentenyl)-

反応式

[O-:1]O.[OH:3][CH2:4]/[CH:5]=[C:6](/[CH3:13])\[CH2:7][CH2:8][CH:9]=[C:10]([CH3:12])[CH3:11]>>[OH:3][CH2:4][CH:5]1[O:1][C:6]1([CH3:13])[CH2:7][CH2:8][CH:9]=[C:10]([CH3:12])[CH3:11]

参加物

反応物 2

HCID 18500Perhydroxyl radical

HCID 643820Nerol

生成物 1

HCID 530403Oxiranemethanol, 3-methyl-3-(4-methyl-3-pentenyl)-

実験手順

The hydroperoxide resulting from nerol can be reduced to the corresponding hydroxyl compound and this can then be cyclized with acid catalysis to give nerol oxide.

出典と根拠

ORDレコード: ord-8e9fb367a1f3464b80c238386c6849bf
出典データセット: uspto-grants-1997_04
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05620569

反応ノート

読み込み中…