関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Styrene | HCID 7501 | — |
| 反応物 | Iodobenzene | HCID 11575 | — |
| 触媒 | Palladium | HCID 23938 | — |
| 触媒 | Tetrabutylammonium Acetate | HCID 82707 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | Stilbene | HCID 11502 | 80% |
反応手順
In a 60 ml miniautoclave, 85 mg of palladium in sol-gel matrix (cf. Example 71, metal content 0.1%) are suspended in 20 ml of DMF. After 2 mmol of iodobenzene, 2 mmol of styrene, and 4 mmol of tetrabutylammonium acetate have been added, heating at 60° C. is performed with shaking. After 12 h, 288 mg of stilbene can be isolated from the reaction solution. This corresponds to an 80% yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05620584 |
|---|
| 出典データセット | uspto-grants-1997_04 |
|---|
| ORD ID | ord-16a1c44fd160492da55c51ef82c842aa |
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| 出典メモ | uspto-grants-1997_04 |
|---|
