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Potassium Carbonate → 2-(2,4,6-Triiodophenoxy)-decane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Potassium Carbonate | HCID 11430 | — |
| 反応物 | 2,4,6-Triiodophenol | HCID 11862 | — |
| 反応物 | Decan-2-yl methanesulfonate | HCID 14916009 | — |
| 反応物 | 2-(2,4,6-Triiodophenoxy)pentadecane | HCID 15343309 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | 2-(2,4,6-Triiodophenoxy)-decane | HCID 15343310 | 75.9% |
反応手順
The 2-methanesulfonyloxydecane (14.8 g, 62.6 mmol), 2,4,6-triiodophenol (29.7 g) 62.9 mmol) and potassium carbonate (8.7 g, 63.0 mmol) were reacted in DMF (210 ml) as per 2-(2,4,6-triiodophenoxy)-pentadecane except at an oil bath temperature of 72° C. for 88 hrs. The reaction was processed as for 2-(2,4,6-triiodophenoxy)-pentadecane to provide a light brown residue. Flash column chromatography (silica, hexanes) provided 2-(2,4,6-triiodophenoxy)-decane (29.1 g, 75.9%) as a white solid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05620677 |
| 出典データセット | uspto-grants-1997_04 |
| ORD ID | ord-1388a0bb205b46dea30b1e71d3f714ba |
| 出典メモ | uspto-grants-1997_04 |