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HRID 53565作成日:2026年10月24日

Z-3-(1,3-dioxan-2-yl)-1-(2-pyridyl)-1-propene → 1-(1,3-Dioxan-2-yl)-3-(2-pyridyl)propane

https://huagongshe.com/ja/reaction/53565

反応式

関与物質

役割名称HCID仕込み量
反応物Z-3-(1,3-dioxan-2-yl)-1-(2-pyridyl)-1-propeneHCID 70113689—
触媒PalladiumHCID 23938—
生成物1-(1,3-Dioxan-2-yl)-3-(2-pyridyl)propaneHCID 1969413992.5%

反応手順

Through a suspension of 800 mg (4.2 mmol) of olefin 149 and 100 mg of 10% palladium on carbon was bubbled a steady stream of hydrogen gas for a period of 10 min. The reaction mixture was then filtered through celite and concentrated to give 805 mg of the acetal 150 as a colorless oil. 1H NMR consistent with structure.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US05620971
出典データセットuspto-grants-1997_04
ORD IDord-bf8ddce61e554c87a399e80c329d67fa
出典メモuspto-grants-1997_04