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4-Phenyl-2-butanol → 4-Methoxybenzyl alcohol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 4-Phenyl-2-butanol | HCID 61302 | — |
| 反応物 | alpha-Methyl-2-pyridinemethanol | HCID 86784 | — |
| 反応物 | 2-Oxido-2-azoniatricyclo[3.3.1.03,7]nonane | HCID 101536640 | — |
| 生成物 | 4-Methoxybenzyl alcohol | HCID 7738 | — |
反応手順
2-(1-Hydroxyethyl)pyridine (76.8 mg, 0.624 mmol) was oxidized in the same manner as that described in Example 8, (a) (except that Nor-AZADO was used at 3 mol %, and the reaction was performed at room temperature) to obtain the objective compound (66.0 mg; yield, 87.4%). The spectrum data were found to be the same as those obtained in Example 6, (h).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08871981B2 |
| 出典データセット | uspto-grants-2014_10 |
| ORD ID | ord-31220d8df9174332927d5f16647c901d |
| 出典メモ | uspto-grants-2014_10 |