Sodium Bicarbonate → HCID 13931210、化合物

HRID 543074ノート

反応式

HRID 543074 の反応式
[Cl-].[CH3:2][O:3][C:4]1[CH:5]=[CH:6][C:7]2[Te:11][CH:10]([CH3:12])[NH2+:9][C:8]=2[CH:13]=1.C(=O)(O)[O-].[Na+]>O>[CH3:2][O:3][C:4]1[CH:5]=[CH:6][C:7]2[Te:11][C:10]([CH3:12])=[N:9][C:8]=2[CH:13]=1

参加物

4

反応物 2

HCID 516892Sodium BicarbonateHCID 198452855-Methoxy-2-methyl-3H-benzotellurazolium Chloride

生成物 1

HCID 13931210HCID 13931210、化合物収率 97%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

5-Methoxy-2-methylbenzotellurazolium chloride (Example 13) (3.7 g=0.012 mole) was suspended in water, sodium bicarbonate in excess of that stoichiometrically required was added, and the free base product was extracted with diethyl ether. After washing with saturated sodium sulfate solution, the organic phase was dried and evaporated under reduced pressure to give a residual oil (3.2 g) which was identified by its nuclear magnetic resonance spectra. C, H, N, O and Te elemental analyses were in agreement with that expected for the structural formula.

後処理

  1. extractionthe free base product was extracted with diethyl ether
  2. washAfter washing with saturated sodium sulfate solution
  3. customthe organic phase was dried
  4. customevaporated under reduced pressure

出典と根拠

ORDレコード
ord-0bb536069f944902a768dcd822791584
出典データセット
uspto-grants-1987_04
特許番号
US04661438

反応ノート

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