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2-Propen-1-yl 1,1,1-trifluoromethanesulfonate → 5,6-Dimethoxy-2-methyl-3-(2-propen-1-yl)benzotellurazolium Trifluoromethanesulfonate

HRID 543085
ノート
印刷プレビュー

反応式

HRID 543085 の反応式
[F:1][C:2]([F:11])([F:10])[S:3]([O:6][CH2:7][CH:8]=[CH2:9])(=[O:5])=[O:4].[CH3:12][O:13][C:14]1[C:15]([O:24][CH3:25])=[CH:16][C:17]2[Te:21][C:20]([CH3:22])=[N:19][C:18]=2[CH:23]=1>C(Cl)(Cl)(Cl)Cl.ClCCl>[F:1][C:2]([F:11])([F:10])[S:3]([O-:6])(=[O:5])=[O:4].[CH3:12][O:13][C:14]1[C:15]([O:24][CH3:25])=[CH:16][C:17]2[Te:21][C:20]([CH3:22])=[N+:19]([CH2:9][CH:8]=[CH2:7])[C:18]=2[CH:23]=1
参加物実験手順後処理出典と根拠反応ノート

参加物

5

反応物 2

HCID 109322232-Propen-1-yl 1,1,1-trifluoromethanesulfonateHCID 139312085,6-Dimethoxy-2-methylbenzotellurazole

生成物 1

HCID 143241435,6-Dimethoxy-2-methyl-3-(2-propen-1-yl)benzotellurazolium Trifluoromethanesulfonate

試薬・触媒・溶媒 2

HCID 5943Carbon Tetrachloride溶媒HCID 6344Dichloromethane溶媒

実験手順

A dried solution of 2-propen-1-yl tri-fluoromethanesulfonate (0.002 mole) in carbon tetrachloride was added dropwise to a solution of 5,6-dimethoxy-2-methylbenzotellurazole (Example 19) (0.50 g, 0.0016 mole) in dichloromethane (25 ml) under a nitrogen atmosphere at room temperature. After the addition was complete, stirring was continued for 7 hours. The solid was isolated by filtration, washed with diethyl ether, and dried at room temperature under vacuum. Yield 0.38 g. A mass spectrogram of the compound was in agreement with that expected for the structural formula.

後処理

  1. additionAfter the addition
  2. customThe solid was isolated by filtration
  3. washwashed with diethyl ether
  4. customdried at room temperature under vacuum

出典と根拠

ORDレコード
ord-c77d63ecb57d46b79b5b9d297ff5355c
出典データセット
uspto-grants-1987_04
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US04661438

反応ノート

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