2-Propen-1-yl 1,1,1-trifluoromethanesulfonate → 2,5,6-Trimethyl-3-(2-propen-1-yl)benzotellurazolium Trifluoromethanesulfonate

HRID 543087ノート

反応式

HRID 543087 の反応式
[CH3:1][C:2]1[Te:3][C:4]2[CH:10]=[C:9]([CH3:11])[C:8]([CH3:12])=[CH:7][C:5]=2[N:6]=1.[F:13][C:14]([F:23])([F:22])[S:15]([O:18][CH2:19][CH:20]=[CH2:21])(=[O:17])=[O:16]>ClCCl>[F:13][C:14]([F:23])([F:22])[S:15]([O-:18])(=[O:17])=[O:16].[CH3:1][C:2]1[Te:3][C:4]2[CH:10]=[C:9]([CH3:11])[C:8]([CH3:12])=[CH:7][C:5]=2[N+:6]=1[CH2:21][CH:20]=[CH2:19]

参加物

4

反応物 2

HCID 109322232-Propen-1-yl 1,1,1-trifluoromethanesulfonateHCID 139312142,5,6-Trimethylbenzotellurazole

生成物 1

HCID 143241452,5,6-Trimethyl-3-(2-propen-1-yl)benzotellurazolium Trifluoromethanesulfonate

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

To a solution of 2,5,6-trimethylbenzotellurazole (Example 22) (9.90 g, 0.0033 mole) in dichloromethane (30 ml) was added the solution of 2-propen-1-yl trifluoromethanesulfonate (0.004 mole) rapidly at room temperature under a nitrogen atmosphere, with good stirring. Solid began separating 10 minutes after the addition was complete. Stirring under a nitrogen atmosphere was continued for about 18 hours. The solid was isolated by filtration, washed with diethyl ether, and dried under vacuum at room temperature. Yield 1.0 g, m.p. 162°-164° C. The mass spectra agreed with the assigned structural formula.

後処理

  1. customSolid began separating 10 minutes
  2. additionafter the addition
  3. customThe solid was isolated by filtration
  4. washwashed with diethyl ether
  5. customdried under vacuum at room temperature

出典と根拠

ORDレコード
ord-1f368f6cdab64480a5779d251a1eee17
出典データセット
uspto-grants-1987_04
特許番号
US04661438

反応ノート

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