化工社化工社 化学情報印刷レポート · 研究参考用
Ethanol → 2-Propenoic acid, 3-(4-chlorophenyl)-, ethyl ester
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ethanol | HCID 702 | — |
| 反応物 | Methanol | HCID 887 | — |
| 反応物 | Styrene | HCID 7501 | — |
| 反応物 | 4-Chlorostyrene | HCID 14085 | — |
| 触媒 | Palladium Chloride | HCID 24290 | — |
| 生成物 | 2-Propenoic acid, 3-(4-chlorophenyl)-, ethyl ester | HCID 201471 | 60.2% |
反応手順
The procedures of Example 27 were exactly followed except that p-chlorostyrene and ethanol were used respectively instead of styrene and methanol and the amount of palladium chloride was changed to 0.1 millimole. Ethyl 4-chlorocinnamate was obtained with a yield of 60.2%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04661620 |
| 出典データセット | uspto-grants-1987_04 |
| ORD ID | ord-6f402cd1951d44a9b4643cffbe16cf59 |
| 出典メモ | uspto-grants-1987_04 |