2-Oxazolidinone → 3-(4-Tert.-butylphenylthio)-oxazolidin-2-one

反応式

[C:1]([C:5]1[CH:10]=[CH:9][C:8]([S:11]Cl)=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2].[O:13]1[CH2:17][CH2:16][NH:15][C:14]1=[O:18]>>[C:1]([C:5]1[CH:10]=[CH:9][C:8]([S:11][N:15]2[CH2:16][CH2:17][O:13][C:14]2=[O:18])=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2]

参加物

反応物 2

HCID 739492-Oxazolidinone

HCID 12801136p-t-Butylbenzenesulfenyl chloride

生成物 1

HCID 130968073-(4-Tert.-butylphenylthio)-oxazolidin-2-one

実験手順

Analogously to Example 4, 2.7 g of 3-(4-tert.-butylphenylthio)-oxazolidin-2-one were obtained as colourless crystals with a melting point of 76° to 81° C. from 4-tert.-butylphenylsulphenyl chloride and oxazolidin-2-one.

出典と根拠

ORDレコード: ord-f819118ee5704277a5b947e4cb90acb3
出典データセット: uspto-grants-1984_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04451475

反応ノート

読み込み中…