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N-bromobutanimide → 2-(Bromomethyl)-3-chloro-1,1'-biphenyl
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | N-bromobutanimide | HCID 67184 | — |
| 反応物 | 3-Chloro-2-methylbiphenyl | HCID 4601832 | — |
| 溶媒 | Carbon Tetrachloride | HCID 5943 | — |
| 生成物 | 2-(Bromomethyl)-3-chloro-1,1'-biphenyl | HCID 13320700 | — |
反応手順
A mixture of 3-chloro-2-methyl[1,1'-biphenyl] (10.4 grams, 0.051 mole) and N-bromosuccinimide (9.2 grams, 0.052 mole) in carbon tetrachloride (150 ml) was heated and irradiated with an infrared lamp for two hours. The mixture was cooled and filtered. The filtrate was evaporated under reduced pressure to give a quantitative yield of 2-bromomethyl-3-chloro[1,1'-biphenyl] as a yellow oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04451484 |
| 出典データセット | uspto-grants-1984_05 |
| ORD ID | ord-c6f05b515ffa4cb4b7c949cce15d8276 |
| 出典メモ | uspto-grants-1984_05 |