1-Fluorenemethanol → 9H-Fluorene 1-methyl 3-(2-chloro-3,3,3-trifluoromethyl-1-propenyl)-2,2-dimethylcyclopropanecarboxylate

HRID 544694

反応式

HRID 544694 の反応式
[C:1]1(CO)[C:13]2[CH2:12][C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.ClC(C(CF)(CF)CF)=C[C@@H]1[C@H](C(Cl)=O)C1(C)C.C1C2CC3C(=CC=CC=3)C=2C=CC=1.[Cl:47][C:48]([C:59]([CH2:64][F:65])([CH2:62][F:63])[CH2:60][F:61])=[CH:49][C@@H:50]1[C@H:52]([C:53]([O:55][CH3:56])=[O:54])[C:51]1([CH3:58])[CH3:57]>>[CH:1]1[C:13]2[CH2:12][C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.[Cl:47][C:48]([C:59]([CH2:60][F:61])([CH2:62][F:63])[CH2:64][F:65])=[CH:49][CH:50]1[CH:52]([C:53]([O:55][CH3:56])=[O:54])[C:51]1([CH3:57])[CH3:58]

参加物

4

反応物 3

HCID 523071-FluorenemethanolHCID 86739269HCID 86739269、化合物HCID 867392759H-fluorene 1-methyl cis-3-(2-chloro-3,3,3-trifluoromethyl-1-propenyl)-2,2-dimethylcyclopropanecarboxylate

生成物 1

HCID 867392739H-Fluorene 1-methyl 3-(2-chloro-3,3,3-trifluoromethyl-1-propenyl)-2,2-dimethylcyclopropanecarboxylate

実験手順

In the manner of Example I, but substituting 9H-fluorene-1-methanol and cis-3-(2-chloro-3,3,3-trifluoromethyl-1-propenyl)-2,2-dimethylcyclopropanecarbonyl chloride, 9H-fluorene-1-methyl cis-3-(2-chloro-3,3,3-trifluoromethyl-1-propenyl)-2,2-dimethylcyclopropanecarboxylate was prepared.

後処理

  1. customwas prepared

出典と根拠

ORDレコード
ord-352319f34ef4448ab01c39d95146bf9a
出典データセット
uspto-grants-1984_05
特許番号
US04451484

関連ノート

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