N-benzyl-1-phenylethylamine → N-benzyl-1-phenylethanimine

HRID 546329ノート

反応式

HRID 546329 の反応式
[CH2:1]([NH:8][CH:9]([C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)[CH3:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.N1C=CC=CC=1.C(OC(=O)C)(=O)C>>[C:11]1([C:9](=[N:8][CH2:1][C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)[CH3:10])[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=1

参加物

3

反応物 2

HCID 519427N-benzyl-1-phenylethylamineHCID 22348678Acetic anhydride pyridine

生成物 1

HCID 297338N-benzyl-1-phenylethanimine

実験手順

Benzyl-(1-phenylethyl)amine, conversion>99%, ee 82% (GC, sample derivatised by treatment with acetic anhydride pyridine, Chirasil DEX CB, 25 m×0.25 mm, injector/detector 200° C., helium 20 psi, 170° C. for 40 minutes then ramp at 15° C./min to 200° C., retention times 29.71 minutes and 30.73 minutes).

後処理

  1. customthen ramp at 15° C./min to 200° C., retention times 29.71 minutes and 30.73 minutes

出典と根拠

ORDレコード
ord-13ba5d3ba5294e9b950de64a67b4ef6c
出典データセット
uspto-grants-2011_05
特許番号
US07935841B2

反応ノート

読み込み中…