5-Ortho-tolylpentene → 1,5-Dimethyltetralin

HRID 546384ノート

反応式

HRID 546384 の反応式
[CH3:1][C:2]1[C:7]([CH2:8][CH2:9][CH2:10][CH:11]=[CH2:12])=[CH:6][CH:5]=[CH:4][CH:3]=1>CC1C=CC=CC=1C>[CH3:12][CH:11]1[C:6]2[C:7](=[C:2]([CH3:1])[CH:3]=[CH:4][CH:5]=2)[CH2:8][CH2:9][CH2:10]1

参加物

3

反応物 1

HCID 108774255-Ortho-tolylpentene

生成物 1

HCID 895161,5-Dimethyltetralin

試薬・触媒・溶媒 1

HCID 7237O-Xylene溶媒

反応条件

温度
120 °C

実験手順

Three hundred milliliters of a solution obtained by mixing o-xylene as a diluent and 5-OTP as a reactant in a weight ratio of 9:1 was introduced into a liquid-phase batch reactor. Then, the mixture was heated to 120° C. at normal pressure by using a mantle. Thereafter, 9 g of the dealuminated zeolite beta catalyst prepared in the above 1 was added to the reaction solution and the resulting mixture was allowed to react under stirring at 200 rpm for 28 hours while maintaining the reaction temperature at 120° C.±1° C. The concentration of the product over the reaction time was analyzed by gas chromatography (Model No.: 6890N, manufactured by Agilent Technologies). The analyzed results for the product were shown in Table 1.

後処理

  1. additionwas introduced into a liquid-phase batch reactor
  2. additionwas added to the reaction solution
  3. customto react
  4. temperaturewhile maintaining the reaction temperature at 120° C.±1° C
  5. customThe analyzed results for the product

出典と根拠

ORDレコード
ord-8df81966f9c04fc68b22a3639772bd60
出典データセット
uspto-grants-2011_05
特許番号
US07935856B2

反応ノート

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