関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 1-Octanethiol | HCID 8144 | — |
| 反応物 | 3,4,4-Trifluoro-3-butenoyl chloride | HCID 10920789 | — |
| 生成物 | 3,4,4-trifluoro-3-butenethioic acid, S-octyl ester | HCID 15239192 | 91.3% |
反応手順
A mixture of 3,4,4-trifluoro-3-butenoyl chloride (1.7 g, 0.0107 mole) and 1-octanethiol (0.72 g, 0.0049 mole) is heated at 70° C. for 12 h. The crude product is purified by passing through a short column of silica gel to give 1.2 g of the desired product as a pale yellow oil, a 91% yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05623084 |
|---|
| 出典データセット | uspto-grants-1997_04 |
|---|
| ORD ID | ord-eb0dbc9d20ca481b847892b364cfb881 |
|---|
| 出典メモ | uspto-grants-1997_04 |
|---|
