Sodium triacetoxyborohydride → 2,4-Dimethyl-4,5,6,7-tetrahydro-thieno[3,2-c]pyridine

反応式

[CH3:1][C:2]1[S:10][C:9]2[CH2:8][CH2:7][N:6]=[C:5]([CH3:11])[C:4]=2[CH:3]=1.C(O[BH-](OC(=O)C)OC(=O)C)(=O)C.[Na+]>>[CH3:1][C:2]1[S:10][C:9]2[CH2:8][CH2:7][NH:6][CH:5]([CH3:11])[C:4]=2[CH:3]=1

参加物

反応物 2

HCID 5049666Sodium triacetoxyborohydride

HCID 218211782,4-Dimethyl-6,7-dihydro-thieno[3,2-c]pyridine

生成物 1

HCID 596630652,4-Dimethyl-4,5,6,7-tetrahydro-thieno[3,2-c]pyridine収率 14%

実験手順

In close analogy to the procedure described above, 2,4-Dimethyl-6,7-dihydro-thieno[3,2-c]pyridine is reacted with sodium triacetoxyborohydride to provide the title compound.

出典と根拠

ORDレコード: ord-10d83a399241424f80c8073a17e051d9
出典データセット: uspto-grants-2011_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07947689B2

反応ノート

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