Sodium Sulfate → 4-((2-(Dimethylamino)ethyl)imino)-2-pentanone

反応式

C[C:2](C)([C:4](=[O:14])[CH2:5][C:6](=[N:8][CH2:9][CH2:10][N:11]([CH3:13])[CH3:12])[CH3:7])C.CC(CC(C)=O)=O.[O-]S([O-])(=O)=O.[Na+].[Na+]>>[CH3:12][N:11]([CH2:10][CH2:9][N:8]=[C:6]([CH3:7])[CH2:5][C:4](=[O:14])[CH3:2])[CH3:13]

参加物

反応物 3

HCID 24436Sodium Sulfate

HCID 31261Acetylacetone

HCID 51050327HCID 51050327、化合物

生成物 1

HCID 136770354-((2-(Dimethylamino)ethyl)imino)-2-pentanone収率 83%

実験手順

In a procedure analogously to 2,2-dimethyl-5-(dimethylaminoethyl-imino)-3-hexanone, starting with starting with 2,4-pentadione (8.00 g, 80.7 mmol), Na2SO4 (14 g, 98.64 mmol), and 3-(dimethylamino)ethylamine (7.83 g, 88.8 mmol). A green liquid was obtained via vacuum distillation at an oil bath of 95-105° C. under 150 mTorr. The yield was 83%. GC analysis indicated one peak.