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1-(3,5-Dibromophenyl)ethanone → (r)-1-(3,5-Dibromo-phenyl)-ethanol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-(3,5-Dibromophenyl)ethanone | HCID 621825 | — |
| 反応物 | (3aS)-1-methyl-3,3-diphenyl-hexahydropyrrolo(1,2-c)(1,3,2)oxazaborole | HCID 2734713 | — |
| 生成物 | (r)-1-(3,5-Dibromo-phenyl)-ethanol | HCID 58539463 | — |
反応手順
1-(3,5-dibromo-phenyl)-ethanone and (S)-(−)-2-methyl-CBS-oxazaborolidine were reacted as described in Example 35, Step 1 to provide (R)-1-(3,5-dibromo-phenyl)-ethanol.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08048902B2 |
| 出典データセット | uspto-grants-2011_11 |
| ORD ID | ord-b3c10ca5ebed4c6b9144bee4098ccb59 |
| 出典メモ | uspto-grants-2011_11 |