化工社化工社 化学情報印刷レポート · 研究参考用
Hydrogen Peroxide → Phenoxathiin, 10-oxide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydrogen Peroxide | HCID 784 | — |
| 反応物 | Water | HCID 962 | — |
| 反応物 | Phenoxathiin | HCID 9217 | — |
| 溶媒 | Acetic Acid | HCID 176 | — |
| 生成物 | Phenoxathiin, 10-oxide | HCID 70360 | 83% |
反応手順
100 g (0.5 mole) of phenoxathiin was dissolved in 1,600 g of acetic acid, after which 48.5 g (0.5 mole) of 35% hydrogen peroxide was added dropwise to the solution. The solution was further stirred for seven days at room temperature. Then, 3,000 g of water was added to the reaction solution to settle out white crystals. The crystals were collected by filtration and dried in vacuum, obtaining the target compound. White crystals, 90 g (yield 83%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08057985B2 |
| 出典データセット | uspto-grants-2011_11 |
| ORD ID | ord-6e7b0c6a3a72493fbcc104d1736eea70 |
| 出典メモ | uspto-grants-2011_11 |