化工社化工社 化学情報印刷レポート · 研究参考用
Hydroxylamine → N-Hydroxy-3-phenylpropanimidamide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydroxylamine | HCID 787 | — |
| 反応物 | 2-Phenylpropionitrile | HCID 15761 | — |
| 反応物 | N'-Hydroxybenzenecarboximidamide | HCID 69186 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | N-Hydroxy-3-phenylpropanimidamide | HCID 53434815 | 70.5% |
反応手順
Phenylpropionitrile (1 g, 7.6 mmol) was reacted with hydroxylamine (50% in water, 0.94 cm3, 15.2 mmol, 2 eq) in EtOH (7.6 cm3) in the same manner as in the preparation of N′-hydroxybenzimidamide (EtOAc used in extraction) to give the product N′-hydroxy-3-phenylpropanimidamide (0.88 g, 70.5%) as a white solid, mp 42-43° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08062429B2 |
| 出典データセット | uspto-grants-2011_11 |
| ORD ID | ord-5ecad023390f445d950b11c47ee3d58a |
| 出典メモ | uspto-grants-2011_11 |