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Hydroxylamine → N'-hydroxy-3-methylbenzimidamide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydroxylamine | HCID 787 | — |
| 反応物 | 3-Tolunitrile | HCID 12104 | — |
| 反応物 | N'-Hydroxybenzenecarboximidamide | HCID 69186 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | N'-hydroxy-3-methylbenzimidamide | HCID 591591 | 97.7% |
反応手順
The reaction of m-tolunitrile (1 g, 8.54 mmol) and hydroxylamine (0.78 cm3, 12.8 mmol, 1.5 eq) in EtOH (8.5 cm3) was performed in the same manner as in the preparation of N′-hydroxybenzimidamide, to give the product N′-hydroxy-3-methylbenzimidamide (1.25 g, 97.7%) as a white solid, mp 92° C. (lit 88-90° C.).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08062429B2 |
| 出典データセット | uspto-grants-2011_11 |
| ORD ID | ord-4d009a67a7424205a959d14cd7c65ff6 |
| 出典メモ | uspto-grants-2011_11 |