Geraniol → 3,7-Dimethyl-1-octanol

HRID 5629

反応式

HRID 5629 の反応式
[CH3:1][C:2](=[CH:4][CH2:5][CH2:6]/[C:7](=[CH:9]/[CH2:10][OH:11])/[CH3:8])[CH3:3]>C(O)C.[Pt]=O>[CH3:8][CH:7]([CH2:6][CH2:5][CH2:4][CH:2]([CH3:3])[CH3:1])[CH2:9][CH2:10][OH:11]

参加物

4

反応物 1

HCID 637566Geraniol

生成物 1

HCID 77923,7-Dimethyl-1-octanol収率 97.5%

試薬・触媒・溶媒 2

HCID 82844Platinum oxide (PtO)触媒HCID 702Ethanol溶媒

実験手順

Geraniol (100 g) was dissolved in ethanol (500 ml), added with platinum oxide (500 mg) and stirred for 24 hours at room temperature under hydrogen atmosphere. After the completion of the reaction, insoluble material was removed by filtration through a Celite layer and the filtrate was concentrated under reduced pressure to obtain 3,7-dimethyloctanol (100 g).

後処理

  1. customAfter the completion of the reaction, insoluble material
  2. customwas removed by filtration through a Celite layer
  3. concentrationthe filtrate was concentrated under reduced pressure

出典と根拠

ORDレコード
ord-c0dfd353e6324d3daf2c3d50805ae08b
出典データセット
uspto-grants-1993_09
特許番号
US05245070

関連ノート

読み込み中…