Methanesulfonic Acid → HCID 25195527、化合物
反応式
[NH2:1][C@@H:2]([CH2:6][O:7][C:8]([O:10][C:11]1[C:16]([CH:17]([CH3:19])[CH3:18])=[CH:15][CH:14]=[CH:13][C:12]=1[CH:20]([CH3:22])[CH3:21])=[O:9])[C:3]([OH:5])=[O:4].[CH3:23][S:24]([OH:27])(=[O:26])=[O:25]>O>[S:24]([OH:27])(=[O:26])(=[O:25])[CH3:23].[NH2:1][C@@H:2]([CH2:6][O:7][C:8]([O:10][C:11]1[C:16]([CH:17]([CH3:18])[CH3:19])=[CH:15][CH:14]=[CH:13][C:12]=1[CH:20]([CH3:22])[CH3:21])=[O:9])[C:3]([OH:5])=[O:4]参加物
4
実験手順
To a suspension of compound (3) (4.44 g, 14.3 mmol) in H2O (100 mL) was added methanesulfonic acid (0.93 mL, 14.3 mmol). The resulting mixture was stirred at room temperature until the solid had completely dissolved. The solution was then frozen and lyophilized to afford the desired product as a light pinkish solid.
後処理
- dissolutionhad completely dissolved
- temperatureThe solution was then frozen