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HRID 56343作成日:2026年10月26日

Acetic Acid → Diacetoxy-butene

https://huagongshe.com/reaction/56343

反応式

関与物質

役割名称HCID仕込み量
反応物Acetic AcidHCID 176—
反応物OxygenHCID 977—
反応物1,3-ButadieneHCID 7845—
反応物1,4-ButanediolHCID 8064—
生成物Diacetoxy-buteneHCID 18688720—

反応手順

It is possible to obtain 1,4BG which is contained in the 1,4-butanediol-containing composition of the present invention by production methods which have hitherto been known. For example, there are included 1,4BG obtained by conducting an acetoxylation reaction using raw material butadiene, acetic acid, and oxygen to obtain diacetoxybutene that is an intermediate and hydrogenating and hydrolyzing the diacetoxybutene; 1,4BG obtained by using maleic acid, succinic acid, maleic anhydride, and/or fumaric acid as a raw material and hydrogenating such a raw material; crude 1,4BG obtained by hydrogenating butynediol obtained by bringing acetylene as a raw material into contact with a formaldehyde aqueous solution; 1,4BG obtained through oxidation of propylene; 1,4BG obtained by hydrogenating succinic acid obtained by a fermentation method; 1,4BG obtained by means of direct fermentation from a biomass such as a sugar, etc.; and the like.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US09434706B2
出典データセットuspto-grants-2016_09
ORD IDord-57dd071250b348eeae137e76768516a2
出典メモuspto-grants-2016_09