化工社化工社 化学情報印刷レポート · 研究参考用
1-Dodecanol → Dodecyl(chlorosulfonyl)carbamate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Dodecanol | HCID 8193 | — |
| 反応物 | Chlorosulfonyl isocyanate | HCID 70918 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | Dodecyl(chlorosulfonyl)carbamate | HCID 10758631 | 101.6% |
反応手順
A solution of n-dodecyl alcohol (10.7 g, 57.4 mmoles) in 100 mL Et2O was added dropwise to a solution of chlorosulfonyl isocyanate (5.0 mL, 57.4 mmoles) in 100 mL Et2O at ~15° C. under an atmosphere of N2. The resulting mixture was stirred for 2 hours and concentrated in vacuo. The residue was triturated with cold hexanes to give a white solid and collected by filtration to give 19.12 g of a white solid, mp 62°-63° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05245068 |
| 出典データセット | uspto-grants-1993_09 |
| ORD ID | ord-0b945865b6ed43e89b1d0e52682f9023 |
| 出典メモ | uspto-grants-1993_09 |