Morpholine → 3-Amino-3-morpholinoacrylonitrile

HRID 565439ノート

反応式

HRID 565439 の反応式
[C:1]([CH2:3][C:4](=[NH:8])OCC)#[N:2].[NH:9]1[CH2:14][CH2:13][O:12][CH2:11][CH2:10]1>C(O)C>[NH2:8][C:4]([N:9]1[CH2:14][CH2:13][O:12][CH2:11][CH2:10]1)=[CH:3][C:1]#[N:2]

参加物

4

反応物 2

HCID 8083MorpholineHCID 256188Ethyl 2-cyanoethanecarboximidate

生成物 1

HCID 27636313-Amino-3-morpholinoacrylonitrile

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

In anhydrous ethanol (10 ml) was dissolved ethyl 2-cyanoacetimidate (1.0 g), followed by addition of morpholine (0.78 g). The mixture was stirred at room temperature for 4 hours, and the separated crystals were collected by filtration. This crystal crop was used as it was in the next reaction.

後処理

  1. filtrationthe separated crystals were collected by filtration
  2. customwas in the next reaction

出典と根拠

ORDレコード
ord-fd12486b577e4589a54a67f04c396b41
出典データセット
uspto-grants-2001_01
特許番号
US06172102B2

反応ノート

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