Hydrochloric Acid → 3-Nitryloxy-2,2-bis(nitryloxymethyl)propionic acid hydrazide

HRID 567932ノート

反応式

HRID 567932 の反応式
[N+:1]([O:4][CH2:5][C:6]([CH2:16][O:17][N+:18]([O-:20])=[O:19])([CH2:11][O:12][N+:13]([O-:15])=[O:14])[C:7](OC)=[O:8])([O-:3])=[O:2].Cl.[NH2:22][NH2:23].Cl>>[N+:1]([O:4][CH2:5][C:6]([CH2:16][O:17][N+:18]([O-:20])=[O:19])([CH2:11][O:12][N+:13]([O-:15])=[O:14])[C:7]([NH:22][NH2:23])=[O:8])([O-:3])=[O:2]

参加物

4

反応物 3

HCID 313Hydrochloric AcidHCID 115031Hydrazinium chlorideHCID 15380869Methyl 2,2-bis(nitryloxymethyl)-3-nitryloxypropionate

生成物 1

HCID 153808743-Nitryloxy-2,2-bis(nitryloxymethyl)propionic acid hydrazide収率 63%

実験手順

1 g (3.5 mmol) of methyl 2,2-bis(nitryloxymethyl)-3-nitryloxypropionate is heated for 5 hours in a water bath with excess aqueous hydrazine hydrochloride solution. The mixture is poured onto ice and weakly acidified with hydrochloric acid. The oil which has deposited is separated by column chromatography to give 3-nitryloxy-2,2-bis(nitryloxymethyl)propionic acid hydrazide (Tri-PA hydrazide) as a colourless oil. Yield: 63%. Elemental analysis: (C: conforms, H: conforms, N: conforms).

後処理

  1. additionThe mixture is poured onto ice
  2. customThe oil which has deposited is separated by column chromatography

出典と根拠

ORDレコード
ord-907267379249417fb39aad15005fd53e
出典データセット
uspto-grants-2001_01
特許番号
US06180664B2

反応ノート

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