N,N'-bis(3-acetylphenyl)pentanediamide → HCID 178466599、化合物

HRID 568150

反応式

HRID 568150 の反応式
[C:1]([C:4]1[CH:5]=[C:6]([NH:10][C:11](=O)[CH2:12][CH2:13][CH2:14][C:15]([NH:17][C:18]2[CH:23]=[CH:22][CH:21]=[C:20]([C:24](=[O:26])[CH3:25])[CH:19]=2)=O)[CH:7]=[CH:8][CH:9]=1)(=[O:3])[CH3:2].[C:28]([NH:31][NH2:32])([NH2:30])=[NH:29].[ClH:33]>CO.Cl.Cl.NNC(N)=N>[ClH:33].[ClH:33].[C:28]([NH:31][N:32]=[C:15]([NH:17][C:18]1[CH:23]=[CH:22][CH:21]=[C:20]([C:24](=[O:26])[CH3:25])[CH:19]=1)[CH2:14][CH2:13][CH2:12][C:11](=[N:32][NH:31][C:28](=[NH:29])[NH2:30])[NH:10][C:6]1[CH:7]=[CH:8][CH:9]=[C:4]([C:1](=[O:3])[CH3:2])[CH:5]=1)(=[NH:30])[NH2:29]

参加物

5

反応物 2

HCID 1010291N,N'-bis(3-acetylphenyl)pentanediamideHCID 178418668HCID 178418668、化合物

生成物 1

HCID 178466599HCID 178466599、化合物収率 98.2%

試薬・触媒・溶媒 2

HCID 178478830HCID 178478830、化合物触媒HCID 887Methanol溶媒

実験手順

N,N′-bis(3-acetylphenyl)pentanediamide (3.66 g), aminoguanidine hydrochloride (2.75 g), and aminoguanidine dihydrochloride (0.05 g) were heated in methanol (35 mL) for 18 hr. Cooling and filtration gave 5.412 g of N,N′-bis(3acetylphenyl)pentanediamide bis(amidinohydrazone) dihydrochloride, mp 187-191° C.

後処理

  1. temperatureCooling
  2. filtrationfiltration

出典と根拠

ORDレコード
ord-2f5ac8b539ba4a04ab8e9caa86f405a3
出典データセット
uspto-grants-2001_01
特許番号
US06180676B2

関連ノート

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