Trimethoxysilane → HCID 89882468、化合物

HRID 571118

反応式

HRID 571118 の反応式
[Si:1]([N:8]([CH2:12][CH2:13][CH2:14][CH3:15])[CH2:9][CH:10]=[CH2:11])([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2].[CH3:16][O:17][SiH:18]([O:21][CH3:22])[O:19][CH3:20]>[Pt].C([Si](C)(C)O[Si](C=C)(C)C)=C.C1(C)C=CC=CC=1>[Si:1]([N:8]([CH2:12][CH2:13][CH2:14][CH3:15])[CH2:9][CH2:10][CH2:11][Si:18]([O:21][CH3:22])([O:19][CH3:20])[O:17][CH3:16])([C:4]([CH3:6])([CH3:7])[CH3:5])([CH3:2])[CH3:3]

参加物

5

反応物 2

HCID 17215TrimethoxysilaneHCID 89882321N-t-butyldimethylsilyl-N-butyl-N-allylamine

生成物 1

HCID 89882468HCID 89882468、化合物

試薬・触媒・溶媒 2

HCID 10959889Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane触媒HCID 1140Toluene溶媒

反応条件

温度
50 °C

実験手順

A flask equipped with a stirrer, reflux condenser, dropping funnel and thermometer was charged with 22.8 g (0.1 mol) of N-t-butyldimethylsilyl-N-butyl-N-allylamine and 0.07 g of a toluene solution of platinum/1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex (Pt concentration 3 wt %) and heated at 50° C. Once the internal temperature became steady, 12.2 g (0.1 mol) of trimethoxysilane was added dropwise over 1 hour. Stirring was continued at the temperature for a further 1 hour. The reaction solution was distilled, collecting 27.3 g of a fraction having a boiling point of 128-129° C./0.4 kPa.

後処理

  1. customA flask equipped with a stirrer
  2. temperaturereflux condenser
  3. distillationThe reaction solution was distilled
  4. customcollecting 27.3 g of a fraction

出典と根拠

ORDレコード
ord-ed8170c273154d789d619e802819ebfb
出典データセット
uspto-grants-2015_05
特許番号
US09024051B2

関連ノート

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