Selectfluor → HCID 10719166、化合物

HRID 571431ノート

反応式

HRID 571431 の反応式
F[B-](F)(F)F.F[B-](F)(F)F.[Cl:11][CH2:12][N+:13]12[CH2:20][CH2:19][N+:16]([F:21])([CH2:17][CH2:18]1)[CH2:15][CH2:14]2.[F:22][P-:23]([F:28])([F:27])([F:26])([F:25])[F:24].[NH4+]>O>[F:22][P-:23]([F:28])([F:27])([F:26])([F:25])[F:24].[F:22][P-:23]([F:28])([F:27])([F:26])([F:25])[F:24].[Cl:11][CH2:12][N+:13]12[CH2:20][CH2:19][N+:16]([F:21])([CH2:17][CH2:18]1)[CH2:15][CH2:14]2

参加物

4

反応物 2

HCID 2724933SelectfluorHCID 9793912Ammonium hexafluorophosphate

生成物 1

HCID 10719166HCID 10719166、化合物収率 101.3%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

To 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (1) (1.06 g, 3.00 mmol, 1.00 equiv) in H2O (9.0 mL) at 23° C. was added ammonium hexafluorophosphate (2.93 g, 18.0 mmol, 6.00 equiv). After stirring for 1 h, the suspension was filtered off and washed with H2O (5×5 mL) and Et2O (10 mL) to afford 1.43 g of the title compound as a colorless solid (quantitative yield).

後処理

  1. filtrationthe suspension was filtered off
  2. washwashed with H2O (5×5 mL) and Et2O (10 mL)

出典と根拠

ORDレコード
ord-d665c7d3bfa1489f8c0a5210573d07a2
出典データセット
uspto-grants-2015_05
特許番号
US09024093B2

反応ノート

読み込み中…