化工社化工社 化学情報印刷レポート · 研究参考用
Water → HCID 178503598、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | Hydrazine hydrate (1:1) | HCID 24654 | — |
| 反応物 | 2-Benzothiazol-2-yl-3,3-bis-methylsulfanylacrylonitrile | HCID 2807727 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | HCID 178503598 | HCID 178503598 | 44% |
反応手順
To a suspension of 2-benzothiazol-2-yl-3,3-bismethylsulfanylacrylonitrile (50 mg, 0.18 mmol) in ethanol (2 mL) was added hydrazine hydrate (15 μL). The mixture was heated to reflux for 2 hours. The reaction mixture was then cooled and water was added. The resulting precipitate was isolated by filtration to yield 21 mg (44%) of the title compound as a yellow solid. MS (m/z, ES+): 263 (M+1, 100%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US09434720B2 |
| 出典データセット | uspto-grants-2016_09 |
| ORD ID | ord-9cdc048960cb4db3b2ca342740adbf80 |
| 出典メモ | uspto-grants-2016_09 |