Trimethoxysilane → N,N-dimethyl-2-(3-(trimethoxysilyl)propoxy)ethanamine

HRID 58000

反応式

HRID 58000 の反応式
[CH2:1]([O:4][CH2:5][CH2:6][N:7]([CH3:9])[CH3:8])[CH:2]=[CH2:3].[CH3:10][O:11][SiH:12]([O:15][CH3:16])[O:13][CH3:14]>C([Si](C)(C)O[Si](C=C)(C)C)=C.[Pt].C1(C)C=CC=CC=1>[CH3:8][N:7]([CH3:9])[CH2:6][CH2:5][O:4][CH2:1][CH2:2][CH2:3][Si:12]([O:15][CH3:16])([O:13][CH3:14])[O:11][CH3:10]

参加物

5

反応物 2

HCID 17215TrimethoxysilaneHCID 261277n,n-Dimethyl-2-(prop-2-en-1-yloxy)ethanamine

生成物 1

HCID 86713993N,N-dimethyl-2-(3-(trimethoxysilyl)propoxy)ethanamine収率 86%

試薬・触媒・溶媒 2

HCID 10959889Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane触媒HCID 1140Toluene溶媒

実験手順

After adding toluene (200 mL) to a round-bottom flask containing 2-(allyloxy)-N,N-dimethylethanamine (0.398 mol) and dissolving trimethoxysilane (0.398 mol), a commercially available platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane solution was added and the mixture was stirred for 24 hours under reflux. Upon completion of reaction, after removing the solvent through distillation under reduced pressure, 0.342 mol (yield: 86%) of the target compound was obtained by extracting with water and diethyl ether. 1H and 13C NMR spectroscopic data of the purified N,N-dimethyl-2-(3-(trimethoxymethylsilyl)propoxy)ethanamine are as follows.

後処理

  1. temperatureunder reflux
  2. customUpon completion of reaction
  3. customafter removing the solvent
  4. distillationthrough distillation under reduced pressure

出典と根拠

ORDレコード
ord-d6f023674b9c4e17b20db89708efa94f
出典データセット
uspto-grants-2016_09
特許番号
US09434751B2

関連ノート

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