化工社化工社 化学情報印刷レポート · 研究参考用
Hydrogen Peroxide → 2,6-Dimethylcyclohexanone
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydrogen Peroxide | HCID 784 | — |
| 反応物 | 2,6-Dimethylcyclohexanol | HCID 21428 | — |
| 反応物 | Sulfuric acid magnesium salt (1:1) | HCID 24083 | — |
| 生成物 | 2,6-Dimethylcyclohexanone | HCID 17780 | 89% |
反応手順
Example 3 was repeated, replacing (-)-menthol by 2,6-dimethylcyclohexanol (6.4 g; 50 mmol), using 5.1 cm3 (60 mmol) of 40% of H2O2, adding 4 g of anhydrous MgSO4 and reducing the reaction time to 30 minutes. 5.61 g (44.5 mmol) of 2,6-dimethyl-cyclohexanone were obtained (GLC purity>99%), which corresponds to a 89% yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04754073 |
| 出典データセット | uspto-grants-1988_06 |
| ORD ID | ord-61b6073f6daa49f6b3ca35fa593931de |
| 出典メモ | uspto-grants-1988_06 |