Epichlorohydrin → HCID 18980716、化合物

HRID 583611ノート

反応式

HRID 583611 の反応式
[OH:1][CH:2]([CH2:17][N:18]([CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH3:47])[CH2:19][CH:20]([OH:35])[CH2:21][NH:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])[CH2:3][NH:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].[CH2:48]([CH:50]1[O:52][CH2:51]1)[Cl:49]>C1(C)C(C)=CC=CC=1>[OH:35][CH:20]([CH2:19][N:18]([CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH3:47])[CH2:17][CH:2]([OH:1])[CH2:3][N:4]([CH2:51][CH:50]([OH:52])[CH2:48][Cl:49])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])[CH2:21][N:22]([CH2:51][CH:50]([OH:52])[CH2:48][Cl:49])[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34]

参加物

4

反応物 2

HCID 7835EpichlorohydrinHCID 18980712HCID 18980712、化合物

生成物 1

HCID 18980716HCID 18980716、化合物収率 99.4%

試薬・触媒・溶媒 1

HCID 7237O-Xylene溶媒

実験手順

A reactor was charged with 16.6 g (0.025 mole) of 15,19-dihydroxy-17-dodecyl-13,17,21-triazatritriacontane obtained in Example 1 and 200 g of xylene, and the contents were kept at 50° C. To the contents, 6.9 g (0.075 mole) of epichlorohydrin was added dropwise over one hour and ten minutes, and the resultant mixture was aged for 36 hours. Thereafter, the solvent and unreacted epichlorohydrin were distilled off under reduced pressure at room temperature, thereby obtaining 21.2 g of 15,19-dihydroxy-13,21-bis(3-chloro-2-hydroxypropyl)-17-dodecyl-13,17,21-triazatritriacontane represented by the following formula. ##STR14##

後処理

  1. customwere kept at 50° C
  2. distillationThereafter, the solvent and unreacted epichlorohydrin were distilled off under reduced pressure at room temperature

出典と根拠

ORDレコード
ord-33d8121217384a17b1cc8a3958544b46
出典データセット
uspto-grants-1999_07
特許番号
US05929283

反応ノート

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