化工社化工社 化学情報印刷レポート · 研究参考用
(3-Bromo-4-methylphenyl)methanol → 3-Bromo-4-methylbenzaldehyde
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | (3-Bromo-4-methylphenyl)methanol | HCID 12947381 | — |
| 触媒 | Manganese oxide | HCID 160959 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | 3-Bromo-4-methylbenzaldehyde | HCID 816765 | 85% |
反応手順
14.4 g (72 mmol) of (3-bromo-4-methylphenyl)methanol are placed in 200 ml of dichloromethane in a round-bottomed flask. 62.6 g (72 mmol) of manganese oxide are added and the medium is stirred at room temperature overnight. The mixture is filtered through Celite and the solvent is evaporated off. 11.8 g (85%) of the expected product are obtained in the form of an oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06924400B2 |
| 出典データセット | uspto-grants-2005_08 |
| ORD ID | ord-20172710c0904141ac8730fb33bb8ee2 |
| 出典メモ | uspto-grants-2005_08 |