OCC(C(OC(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)OC)CC[N:6]1[C:14]([NH:15]C(C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)=[N:13][C:12]2C1=NC(OC)=[N:10][CH:11]=2.[C:60]([O:68][C:69](=O)[C:70]1[CH:75]=[CH:74]C=C[CH:71]=1)(=[O:67])[C:61]1[CH:66]=[CH:65][CH:64]=[CH:63][CH:62]=1.C[OH:78].C[N:80]([CH3:83])[CH:81]=O>CN(C)C1C=CN=CC=1>[NH2:15][C:14]1[N:6]=[C:83]2[C:11]([N:10]=[CH:81][N:80]2[CH2:74][CH2:75][CH:70]([CH2:71][OH:78])[CH2:69][O:68][C:60](=[O:67])[C:61]2[CH:62]=[CH:63][CH:64]=[CH:65][CH:66]=2)=[CH:12][N:13]=1To a solution of 9-(3-hydroxymethyl-4-monomethoxytrityloxybut-1-yl)-2-monomethoxytritylaminopurine (0.70 g, 0.9 mmol) and 4-dimethylaminopyridine (10 mg) in N,N-dimethylformamide (5 ml) was added benzoic anhydride (0.61 g, 2.7 mmol) and the solution was stirred for 1 hour. Methanol (1 ml) was added and the solvent was removed. The residue was taken up in 80% acetic acid (9 ml) and the solution was stirred at 80° for 20 minutes. Water (3 ml) was added and the solution was extracted with hexane (2×10 ml). The aqueous layer was retained and the solvent was removed. The residue was partitioned between saturated aqueous sodium bicarbonate and chloroform and the organic layer was dried (magnesium sulphate) and the solvent removed. The residue was purified by column chromatography on silica gel eluting with chloroform-methanol (14:1) to afford 2-amino-9-(4-benzoyloxy-3-hydroxymethylbut-1-yl)purine which was obtained as a white crystalline solid after trituration with methanol (235 mg, 76%), m.p. 116°-118°; λmax (MeOH) 223 (36,700) and 309 (6,680)nm; νmax (KBr) 3320, 1710, 1610, and 1580 cm-1 ; δH [(CD3)2SO]1.83 (1H, m, 3'-H), 1.93 (2H, q, J 7.1 Hz, 2'-H), 3.52 (2H, t, J 5.3 Hz, D2O exchange gives d, CH2OH), 4.19 (2H, t, J 7.0 Hz, 1'-H), 4.2-4.3 (2H, ABX, JAB 11.0 Hz, JAX =JBX 5.6 Hz, CH2OOC), 4.69 (1H, t, J 5.2 Hz, D2O exchangeable, OH), 6.43 (2H, s, D2O exchangeable, 2-NH2), 7.5-7.9 (5H, m, C6H5), 8.10 (1H, s, 8-H), and 8.55 (1H, s, 6-H); (Found: C, 59.20; H, 5.63; N, 20.82%. C17H19N5O3 requires C, 59.81; H, 5.61; N, 20.52%).
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